BJXLC - CARBON DIOXIDE

Product Identification

Product ID:CARBON DIOXIDE
MSDS Date:07/01/1986
FSC:6830
NIIN:00-281-3053
MSDS Number: BJXLC

Responsible Party
UNION CARBIDE CORP INDUSTRIAL CHEMICALS DIV
39 OLD RIDGEBURY ROAD
DANBURY, CT 06817-0001
US

Emergency Phone: 800-822-4357

Info Phone: 800-822-4357

Cage: 61637

Contractor
ZODIAC OF NORTH AMERICA INC
400 STEVENSVILLE, MD 21666-9301 US

Telephone: 303-777-6671

Cage: 60042

Ingredients

CARBON DIOXIDE

CAS: 124-38-9

RTECS: FF6400000

Fraction By Weight: 100%

OSHA PEL 5000 PPM

ACGIH TLV: 5000PPM/30000STEL;93

Hazards

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE-EYES:VAPOR, STINGING
SENSATION;LIQUID, FROSTBITE.SKIN:LIQUID, FROSTBITE.INHALATION:LOW
OXYGEN IN BLOOD.MODERATE CONCENTRATIONS MAY CAUSE
HEADACHE,DIZZINESS,EXCITATION,VOMITING UNCONSCIOUSNESS.LA CK OF
OXYGEN CAN CAUSE DEATH.INGESTION OF LIQUID:FROSTBITE O LIPS
&MOUTH.CHRONIC:NO ADVERSE EFFECTS.
Explanation of Carcinogenicity:NONE OF THE COMPOUNDS IN THIS PRODUCT IS
LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN.
Effects of Overexposure:EYE & SKIN CONTACT WITH LIQUID MAY CAUSE
FROSTBITE.INHALATION MAY CAUSE DROWSINESS,STINGING OF THE NOSE AND
THROAT,RAPI BREATHING,EXCESS SALIVATION AND VOMITING.DEATH CAN
OCCUR DUE TO LACK OF OXYGEN.S WALLOWING IS A HIGHLY UNLIKELY ROUTE
OFEXPOSURE.DAMAGE TO RETINAL CEL AND CENTRAL NERVOUS SYSTEMS MAY
OCCUR.
Medical Cond Aggravated by Exposure:UNLIKELY

First Aid

First Aid:EYE:FLUSH W/WATER 15 MIN,HOLD LIDS OPEN.CALL A
DOCTOR.SKIN:WARM FROSTBITE AREA WITH WARM WATER(NOT TO EXCEED
105F).CALL A PHYSICIAN.INHALED:REMOVE TO FRESH AIR.GIVE CPR/OXYGEN
IF NECESSARY.CALL A DOCT OR.INGESTION:THIS PRODUCT IS A GAS AT
NORMAL TEMPERATURE AND PRESSURE.

Fire Fighting

Extinguishing Media:CARBON DIOXIDE CANNOT CATCH FIRE. USE MEDIA
APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:EVACUATE ALL PERSONNEL FROM DANGER
AREA.IMMEDIATELY DELUGE CONTAINERS WITH WATER SPRAY FROM MAXIMUM
DISTANCE UNTI COOL,THEN MOVE CONTAINERS AWAY FROM FIRE AREA
Unusual Fire/Explosion Hazard:CONTAINERS MAY RUPTURE DUE TO HEAT OF
FIRE.CONTAINER SHOULD NOT BE KEPT AT A TEMPERATURE HIGHER THAN
125F.MOST CONTAINERS HAVE PRESSURE RELIEF DEVICES TO VENT.

Accidental Release

Spill Release Procedures:EVACUATE ALL PERSONNEL FROM DANGER AREA.USE
SELF-CONTAINED BREATHING APPARATUS WHERE NEEDED.SHUT OFF LEAK IF
WITHOUT RISK.VENTILATE AREA.
Neutralizing Agent:NONE

Handling

Handling and Storage Precautions:STORE IN A COOL,DARK,WELL VENTILATED
AREA.KEEP CONTAINERS TIGHTLY CLOSED.NEVER WORK ON A PRESSURIZED
SYSTEM.IF THERE IS A LEAK,RELEASE PRESSURE FIRST.
Other Precautions:CAUTION:HIGH PRESSURE LIQUEFIED GAS.CAN CAUSE RAPID
SUFFOCATION.CARBON DIOXIDE IS HEAVIER THAN AIR.IT DISPLACES AIR
UPWARD AND CREATES AN OXYGEN-DEFICIENT ATMOSPHERE.VENTILATE SPACE
BEFORE ENTRY.VERIF Y SUFFICIENT OXYGEN CONCENTRATION.

Exposure Controls

Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATORS. SEE 29 CFR
1910.134 FOR REGULATIONS PERTAINING TO RESPIRATOR USE.
Ventilation:LOCAL EXHAUST IS PREFERRED. MECHANICAL (GENERAL) IS
ACCEPTABLE.
Protective Gloves:NEOPRENE
Eye Protection:IN ACCORDANCE WITH OSHA 29 CFR 1910.133
Other Protective Equipment:METATARSAL SHOES FOR CYLINDER HANDLING.EYE
WASH STATION AND SAFETY SHOWER.
Work Hygienic Practices:USE GOOD CHEMICAL HYGIENE PRACTICE. AVOID
UNNECESSAR CONTACT.
Supplemental Safety and Health
NOTE TO PHYSICIAN:THERE IS NO SPECIFIC ANTIDOTE. TREATMENT OF
OVEREXPOSURE SHOULD BE DIRECTED AT THE CONTROL OF SYMPTOMS AND THE
CLINICAL CONDITION. MSDS BUILT BY DGSC-SSH FROM SAME ITEM,
DIFFERENT N SN.

Chemical Properties

HCC:G3
Boiling Pt:B.P. Text:-109F,-78C
Vapor Pres:42928 @21C
Vapor Density:1.522
Evaporation Rate & Reference:HIGH (N-BUTYL ACETATE=1)
Solubility in Water:SLIGHT
Appearance and Odor:COLORLESS GAS AT NORMAL TEMPERATURE AND
PRESSURE;ODORLESS
Percent Volatiles by Volume:100

Stability

Stability Indicator/Materials to Avoid:YES
ALKALI METALS, ALKALINE EARTH METALS, METAL ACETYLIDES,CHROMIUM,
TITANIUM ABOVE 550C, URANIUM ABOVE 750C
Stability Condition to Avoid:HIGH TEMPERATURE AND FLAME
Hazardous Decomposition Products:IN THE PRESENCE OF AN ELECTRICAL
DISCHARGE,CARBON DIOXIDE IS DECOMPOSED TO FORM CARBON MONOXIDE AND
OXYGEN.

Disposal

Waste Disposal Methods:DISPOSE I/A/W ALL FEDERAL, STATE AND LOCAL
REGULATIONS MANUFACTURER SUGGESTS THAT DISPOSAL MAY BE DONE BY
SLOWLY RELEASING INTO ATMOSPHERE OUTDOORS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.